PREPARATION AND CHARACTERIZATION OF N-SUBSTITUTED OCTANOHYDROXAMIC ACIDS METAL COMPLEXES

Document Type : Original Article

Authors

1 Chemistry Department, Faculty of Science, Garyounis University.

2 Chemistry Department, Faculty of Science, Omar El Mokhtar University.

Abstract

Organic ligands of octano, N-methyl, N-phenyl, N-(p-chloro phenyl) octano-hydroximic acids were prepared. The interaction of such ligands with La(III), Co(IV), Th(IV), ZrO(II) and UO2(II) ions under pH control  in (1:1), (1:2) and (1:3) Molar ratios (M:L) led to the formation of solid complexes which gave analytical data suggested the (1:1), (1:2) and (1:3) based on elemental analysis, IR and 1HNMR techniques.